Publikasjoner
NIBIOs ansatte publiserer flere hundre vitenskapelige artikler og forskningsrapporter hvert år. Her finner du referanser og lenker til publikasjoner og andre forsknings- og formidlingsaktiviteter. Samlingen oppdateres løpende med både nytt og historisk materiale. For mer informasjon om NIBIOs publikasjoner, besøk NIBIOs bibliotek.
2025
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Forfattere
Christophe Moni Eva Farkas Claire Coutris Hanna Marika Silvennoinen Anders Aas Marit Almvik Liang Wang Kathinka Lang Liu Xingang Marianne StenrødSammendrag
Biochar and pesticides are likely to be increasingly used in combination in agricultural soils, yet their combined effects on climate change mitigation remain unexplored. This study presents an 8-month incubation experiment with different soil types (silt loam and sandy loam), biochars (corncob and corn stem), and pesticides (with and without a pesticide mixture), during which CO2 production from soil organic matter (SOM) and biochar mineralisation was monitored using isotopic methods. A comprehensive modelling approach, describing all mineralisation results over the entire incubation with a reduced set of parameters, was employed to isolate the effects of biochar, pesticides, and their interactions across soil types and carbon pools, and captured the dynamic effect of biochar on SOM mineralisation. Over 99.5% of biochars remained inert after 8 months, confirming the role of biochar as a carbon sequestration technology. Biochar addition showed higher SOM stabilisation potential in soil with high clay content compared to soil with low clay content. This suggests that biochar amendment should be considered carefully in clay-depleted soils, as it could result in a loss of native SOM. Corn stem biochar, characterised by high surface area and low C/N ratio, demonstrated higher SOM stabilisation potential than corncob biochar with low surface area and high C/N ratio. Pesticide application reduced SOM mineralisation by 10% regardless of soil and biochar types. Finally, the interaction between corncob biochar and pesticides further reduced SOM mineralisation by 5%, while no interactive effect was observed with corn stem biochar. These findings highlight the importance of considering biochar-pesticide interactions when evaluating the impact of biochar amendments on native SOM stability.
Forfattere
Claire CoutrisSammendrag
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Forfattere
Begüm Bilgiç Judit Sandquist Svein Jarle Horn Lu Feng Cecilie Græsholt Asmira Delic Roger Antoine Khalil Michal SposobSammendrag
Digestate, a key byproduct of anaerobic digestion (AD), holds residual methane potential (RMP) that must be stabilized or recovered to prevent greenhouse gas emissions after field use. Thermal hydrolysis (TH), typically a pretreatment for AD, improves biogas production. This study assesses RMP in digestates from food waste (FW) and sewage sludge (SS) biogas plants, treated with TH at 160 and 190 °C. For the liquid fraction, FW digestate at 160 °C yielded 1.5 times more methane than untreated digestate, while SS digestate showed a threefold increase. The solid fraction of FW digestate at 160 °C had 1.4 times higher methane yield than untreated, but SS digestate produced less methane after TH. Adding sulfuric acid after TH increased phosphate release but reduced methane production in both digestates. Overall, TH as a post-treatment enhanced organic content release into the liquid fraction, enhancing methane yield, while acid addition improved phosphorus solubility, thereby enhancing digestate's nutrient value.
Sammendrag
Upgrading biogas to biomethane could contribute to sustainable energy production, yet H2S may reduce the process efficiency and gas quality. This work examined the impact of H2S on biomethanation in batch assays and in continuous trickle bed reactor (TBR). The batch assay (not biofilm based) was conducted to quickly determine the threshold H2S concentration and to evaluate the inoculum's response to repeated H2S exposure. In contrast, the TBR experiment aimed to explore the role of biofilm-based biomethanation in mitigating H2S inhibition. Batch assays revealed significant inhibition, especially at higher H2S concentrations (3 %) and thermophilic temperatures (51 °C). In the batch assay, presence of H2S resulted in up to 30 % reduction in CH4 yield, decreasing from 229 to 160 NmL/Lreactor. Additionally, the CH4 content declined by 12 %, from 49 to 43 %. In contrast, TBRs showed resilience where TBRs fed with H2S-rich biogas produced effluent gas with 83.5 % CH4, similar to control (81.0 %). 16S rRNA analysis highlighted shifts toward sulphate reducing and sulphur oxidizing bacteria under H2S exposure, while acetogenic and syntrophic acetate-oxidizing bacteria increased in the control. This suggests potential competition for available substrates when subjected to H2S. These findings highlight that H2S significantly inhibits non-biofilm-based biomethanation, as seen in batch assays, although moderate acclimation was observed. However, biofilm-based process, e.g TBRs, effectively mitigate H2S toxicity, ensuring efficient biogas upgrading to biomethane.