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Publikasjoner

NIBIOs ansatte publiserer flere hundre vitenskapelige artikler og forskningsrapporter hvert år. Her finner du referanser og lenker til publikasjoner og andre forsknings- og formidlingsaktiviteter. Samlingen oppdateres løpende med både nytt og historisk materiale. For mer informasjon om NIBIOs publikasjoner, besøk NIBIOs bibliotek.

2007

Sammendrag

Despite the fact that creosote mainly consists of polycyclic aromatic hydrocarbons (PAHs), more polar compounds like phenolics, benzenes and N-, S-, O-heterocyclics dominate the groundwater downstream from creosote-contaminated sites. In this study, bioassay-directed fractionation, combined with fullscan GC-MS, identified organic toxicants in creosote-contaminated groundwater. An organic extract of creosote-contaminated groundwater was fractionised on a polar silica column using high performance liquid chromatography (HPLC), and the toxicity of the fractions was measured by the Microtox®-bioassay. PAHs, which comprise up to 85% of pure creosote, accounted for only about 13% of total toxicity in the creosote-contaminated groundwater, while methylated benzenes, phenolics and N-heterocyclics accounted for ca. 80% of the measured toxicity. The fraction containing alkylated quinolines was the most toxic single fraction, accounting for 26% of the total measured toxicity. The results imply that focus on PAHs may underestimate risks associated with creosote-contaminated groundwater, and that environmental risk assessment should focus to a higher degree on substituted PAHs and phenolics because they are more toxic than the unsubstituted ones. Additionally, benzenes and N-heterocyclics (e.g. alkylated quinolines) should be assessed.