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NIBIOs employees contribute to several hundred scientific articles and research reports every year. You can browse or search in our collection which contains references and links to these publications as well as other research and dissemination activities. The collection is continously updated with new and historical material.

2024

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Abstract

To better characterize properties governing the sorption of per- and polyfluoroalkyl substances (PFAS) to biochar, twenty-three diverse biochars were characterized and evaluated as sorbents for perfluorooctanoic acid (PFOA). Biochars were produced at various temperatures, using two different technologies, and made from sewage sludge, food waste reject, wood wastes, and one reference substrate (wood pellets). The biochars were characterized in terms of surface area, pore volume and pore size distributions, elemental composition, leachable elements, ash content, pH, zeta potential, condensed aromatic carbon (ConAC) content (determined by benzenepolycarboxylic acid (BPCA) markers), and their -OH functional group content (infrared spectroscopy). PFOA sorption isotherms were determined using Polanyi-Dubinin-Manes (PDM) and Freundlich models. The sludge-based biochars [Freundlich coefficients (log KF) between 2.56 ± 0.11 and 6.72 ± 0.22 (μg/kg)/(μg/L)nF; fitted free energy of adsorption (E) and pore volume (Vo) from the PDM model between 13.27 and 17.26 kJ/mol, and 0.50 and 523.51 cm3/kg] outperformed wood biochars [log KF between 1.02 and 4.56 ± 0.22 (μg/kg)/(μg/L)nF; E between 9.87 and 17.44 kJ/mol; Vo between 0.21 and 7.16 cm3/kg] as PFOA sorbents. Multivariate statistical analysis revealed that the sorption capacity was mainly controlled by pore volume within the pore diameter region that could accommodate the molecular size of PFOA (3–6 nm). Hydrophobic interactions between PFOA and aromatic carbon rich regions controlled sorption affinity, especially in the wood biochars.

Abstract

Female flowering and cone production took place in three Norway spruce progeny tests at ages 17 and 20 years, each planted with full-sib families from a half diallel. The number of cones on individual trees were scored in five classes. More than 50 % of the trees produced cones, and a considerable variation was found among families for the ability to produce cones (precocity) and for the number of clones scored in classes (fruitfulness). Both traits were strongly related to tree heights and diameters at the individual and at the family level. In general, tall trees produced the highest number of cones. However, some families produced many cones even if their average heights were low. In two of the half diallels, estimates of GCA variance components for the number of cones produced had twice the value of the SCA component, indicating additive genetic inheritance of cone production. Heritability estimates of cone scores were 0.10, 0.17 and 0.23, and the genetic correlations between cone production and tree heights were 0.40, 0.50 and 0.35 in the three half-diallels, respectively.