Thomas Hartnik
Divisjonsdirektør
(+47) 926 94 021
thomas.hartnik@nibio.no
Sted
Ås - Bygg O43
Besøksadresse
Oluf Thesens vei 43, 1433 Ås (Varelevering: Elizabeth Stephansens vei 23)
Biografi
Utdanning:
Doktorgrad (Dr.scient) i økotoksikologi fra Norges Miljø- og biovitenskapelige Universitet i 2008
Kompetanseområder:
- ledererfaring med personal- og fagansvar,
- variert yrkesbakgrunn fra akademia, statlig forvaltning og privat næringsliv innen sirkulær økonomi og forurensnings- og klimarelaterte problemstillinger.
- Prosjektleder for større FoU- og konsulentprosjekter.
- Erfaring fra styrer i Norges Forskningsråd og faglige nettverk
Forfattere
Øyvind Skreiberg Einar Stuve Halvor Mortensen Ase-Lill Fossan Østli Steinar Danielsen Michael Undrum Lasse Gunnerud Jon Rune Vetleseter Thomas Hartnik Pål Jahre Nilsen Bjørn Moldskred André Monsrud Geir Markussen Mia Ulvin Alexandra Roos RassatSammendrag
Det er ikke registrert sammendrag
Forfattere
Karen Ane Frøyland Skjennum Katinka Muri Krahn Erlend Sørmo Raoul Wolf Aleksandar I. Goranov Patrick G. Hatcher Thomas Hartnik Hans Peter Heinrich Arp Andrew R. Zimmerman Yaxin Zhang Gerard CornelissenSammendrag
To better characterize properties governing the sorption of per- and polyfluoroalkyl substances (PFAS) to biochar, twenty-three diverse biochars were characterized and evaluated as sorbents for perfluorooctanoic acid (PFOA). Biochars were produced at various temperatures, using two different technologies, and made from sewage sludge, food waste reject, wood wastes, and one reference substrate (wood pellets). The biochars were characterized in terms of surface area, pore volume and pore size distributions, elemental composition, leachable elements, ash content, pH, zeta potential, condensed aromatic carbon (ConAC) content (determined by benzenepolycarboxylic acid (BPCA) markers), and their -OH functional group content (infrared spectroscopy). PFOA sorption isotherms were determined using Polanyi-Dubinin-Manes (PDM) and Freundlich models. The sludge-based biochars [Freundlich coefficients (log KF) between 2.56 ± 0.11 and 6.72 ± 0.22 (μg/kg)/(μg/L)nF; fitted free energy of adsorption (E) and pore volume (Vo) from the PDM model between 13.27 and 17.26 kJ/mol, and 0.50 and 523.51 cm3/kg] outperformed wood biochars [log KF between 1.02 and 4.56 ± 0.22 (μg/kg)/(μg/L)nF; E between 9.87 and 17.44 kJ/mol; Vo between 0.21 and 7.16 cm3/kg] as PFOA sorbents. Multivariate statistical analysis revealed that the sorption capacity was mainly controlled by pore volume within the pore diameter region that could accommodate the molecular size of PFOA (3–6 nm). Hydrophobic interactions between PFOA and aromatic carbon rich regions controlled sorption affinity, especially in the wood biochars.
Forfattere
Erlend Sørmo Katinka Muri Krahn Gudny Øyre Flatabø Thomas Hartnik Hans Peter Heinrich Arp Gerard CornelissenSammendrag
Biomass pyrolysis is the anoxic thermal conversion of biomass into a carbon rich, porous solid, often called biochar. This could be a better waste management alternative for contaminated organic wastes than incineration, due to the useful properties of biochar and potential for carbon sequestration. There are, however, concerns about the potential formation/destruction of polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs) and polychlorinated dibenzo-p-dioxins and furans (PCDD/Fs). Six organic wastes, including digested sewage sludges, wood wastes, and food waste reject, were pyrolyzed (500–800°C) in a full-scale relevant unit (1–5 kg biochar hr−1). Removal efficiencies for PCBs and PCDD/Fs were > 99% in the produced biochars. Biochar PAH-content (2.7–118 mgkg−1) was not significantly correlated to feedstock or temperature. PAHs (2563–8285 mgkg−1), PCBs (22–113 µgkg−1), and PCDD/Fs (1.8–50 ngTEQ kg−1) accumulated in the pyrolysis condensate, making this a hazardous waste best handled as a fuel for high temperature combustion. Emission concentrations for PAHs (0.22–421 µgNm−3) and PCDD/Fs (≤2.7 pgTEQ Nm−3) were mainly associated with particles and were below the European Union’s waste incineration thresholds. Emission factors ranged from 0.0002 to 78 mg tonne−1 biochar for PAHs and 0.002–0.45 µgTEQ tonne−1 biochar for PCDD/Fs. PCDD/F-formation was negligible during high temperature (≥500 °C) biomass pyrolysis (69–90% net loss)