Publications
NIBIOs employees contribute to several hundred scientific articles and research reports every year. You can browse or search in our collection which contains references and links to these publications as well as other research and dissemination activities. The collection is continously updated with new and historical material.
2007
Authors
Aaron SmithAbstract
No abstract has been registered
Abstract
The aim of this study was to use Energy-Dispersive X-ray Spectroscopy (EDS) to localize chitosan in the cell wall of chitosan impregnated Scots pine. It is of both general and specific interest to investigate the concentration of chitosan in the wood matrix to gain further knowledge and understanding of chitosan as a wood protective system.After deacetylation, chitosan was re-acetylated with chloroacetic anhydride to achieve a covalent bonding of chloride to the chitosan polymer. Chloride labeled chitosan was measured by EDS using a Scanning Electron Microscope (SEM) and described in apparent concentration of chloride. Analysis for free chloride anions was tested by dialysis and ion chromatography.There was a significant correlation between the molecular weight of chitosan and the apparent concentration of covalent bonded chloride to the chitosan polymer. High molecular weight chitosan showed a better interaction with the cell wall structure than low molecular chitosan.
Abstract
Furfurylated wood is an environmentally friendly, chemically treated, wood product with improved characteristics. Quality control of furfurylated wood is still performed manually by subtracting the initial weight of a treated sample from its final weight, then dividing the result by the initial weight. Expressed as a percentage, this results in a value that represents the weight percent gain (WPG) of the treated sample and thus the degree of modification. The major disadvantage of this quality control method is that the production parameters are needed to determine WPG, since the initial weight cannot be deduced from a treated wood sample. In this paper the use of ThermoGravimetric Analysis (TGA) is presented as a potential quality control method for furfurylated Scots pine (Pinus sylvestris L.). The technique is independent of production parameters and, therefore, enables third parties to determine the WPG of any furfurylated wood product. Three validation trials have been performed with the same validation samples, but varying TGA settings and with different Partial Least Square regression models (PLS-models). Although the method needs further improvement, it has shown good accuracy and precision. Therefore, it is con
Abstract
Furfurylated wood (wood modified by furfuryl alcohol) has over the last years gained marked shares from both tropical wood and conventional preservative treated wood and this has, in turn, generated several research projects concerning process development. The impregnation of spruce is well known from literature to be a difficult task. Furthermore, the sapwood of Scandinavian grown Scots pine is also known to be difficult to fully impregnate from time to time. The primary objective of the study was to evaluate whether the Oscillating Pressure Method (OPM) could be used to impregnate green and dry Norway spruce wood (Picea abies) with a Furfuryl alcohol (FA) - mixture. The secondary objective of the study was to evaluate if OPM could improve the penetration of FA in Scots pine (Pinus sylvestris) as compared to conventional full cell (Bethell) treatment. Impregnation tests were carried out on boards and planks as well as 300 mm and 500 mm clear wood samples. Samples were removed for MC measurement and the initial weight of the test samples was determined. Four different impregnation schemes were tested. The results indicate that Norway spruce can be impregnated by the OPM method to produce a protective shell of treated wood around a core of untreated wood. The penetration in Spruce showed great variation between different boards and between different parts of the individual boards. This is in part expected, but can also be caused by uncontrolled pre drying of the test material which was stacked uncovered after sawing. For Scots pine, the OPM improved the penetration of both sapwood and, to some extent, the outer heartwood.
Abstract
The objective was to evaluate whether Lowry-impregnation of Scots pine with FA100-mix, instead of the FA40-mix, would lead to similar or slightly higher WPGs and to investigate any potential changes in penetration pattern. The results indicate that the penetration was better, also penetrating the outer zone of the heartwood. Furthermore, it was possible to reduce the WPG-levels for pine down to 50-70% (corresponding to PFA retentions of 260- 315 kg/m³) from 120% (approx. 550 kg/m³) with full-cell impregnation using FA100-mix. Using the Lowry process with FA100-mix would probably be a possible treating schedule for products aimed for use in ground contact. The reduced content of hygroscopic salts in the furfurylated wood product would also further reduce hygroscopisity compared with FA-40 mix. However, more trials are needed in order to optimize penetration while still keeping the final WPG low.
Abstract
After two decades of monitoring forest health in Europe, in response to concern for negative effects of air pollution, a similar worry is now increasing in China. In a co-operative project between Chinese and Norwegian researchers a forest monitoring was implemented in the acid rain region in south China. During 2000–2004 two small watersheds were monitored: TieShanPing (TSP) near ChongQing City and LuChongGuan (LCG) near GuiYang City. They are covered by Masson pine (Pinus massoniana) forest. The methodology of the European intensive forest monitoring programme (ICP-Forests level-II) was adopted; including crown assessments, foliar chemistry, air and soil chemistry, and more. This paper presents results of this co-operative project. Considerable forest damage was revealed by monitoring the crown condition of Masson pine trees. The average defoliation percentage for all assessed trees (predominant, dominant and co-dominant pines, corresponding to Kraft classes 1–3) in the more acidified TSP was over 40% and remained stable throughout the monitoring period, accompanied by an extremely high mortality in some years. In contrast, the defoliation in the less acidified LCG was relatively low but increased considerably, from 16% to around 40%, within the 4 monitoring years. The significance of air pollution for the forest damage remains uncertain. The annual SO2 concentration in TSP and LCG is about 2 and 4 times higher than the critical level of 20 μg m−3 given in the LRTAP convention for effects on forests. Therefore the air pollution effects cannot be ruled out as contributing factors for forest damage. However, this cannot be substantiated based on the presented monitoring data since none of the specific symptoms of air pollution damage were observed. Furthermore, an analysis of the monitoring data did not reveal any significant correlation between defoliation and the soil chemical properties. It is noteworthy that the evident agents that were identified are capable of causing the observed forest damage. These agents were insect attacks and climatic stress. It is possible that the forest damage has complex causes.
Authors
John Derome Per Arild Aarrestad Paul Aspholm Vegar Bakkestuen Jarle Werner Bjerke Kjell Einar Erikstad Minna Hartikainen Ludmila Isaeva Martti Lindgren Antti-Jussi Lindroos Tor Myking Jarmo Poikolainen Pasi Rautio Ingvald Røsberg Maija Salemaa Hans Tømmervik Natalya VassilievaAbstract
No abstract has been registered
Abstract
No abstract has been registered
Abstract
In Norway exterior wood structures have traditionally nearly exclusively been made of treated and untreated Picea abies and Pinus sylvestris. In recent years there has been a tendency that other tree species, like various domestic hardwoods and imported species have been used in exterior above ground applications, often unfinished. For several wood species, especially hardwoods, information regarding the durability in use class 3 is lacking. The main objective of this paper is to evaluate natural durability of Norwegian wood species for above ground applications comparing two non-standard above ground tests with the European standard tests for soil contact (EN 252) and lab performance against basidiomycetes (EN 113). The European standard tests EN 113 and EN 252 gave quite similar results, and they also corresponded well with the natural durability classification in EN 350-2. The two non-standard above ground tests differed to some extend from EN 113, EN 252 and EN 350-2. The results indicate that natural durability classification for one single wood species can change depending on use class. However, the field trials need a longer period of time before a final classification can be performed. Four species not included in EN 350-2 were classified in this study: Juniperus communis (1), Salix caprea (5), Sorbus aucuparia (5) and Populus tremula (5).
Abstract
No abstract has been registered