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Publications

NIBIOs employees contribute to several hundred scientific articles and research reports every year. You can browse or search in our collection which contains references and links to these publications as well as other research and dissemination activities. The collection is continously updated with new and historical material.

2005

Abstract

In recent years chitosans have been investigated as a natural chemical for wood preservation against fungal decay, and chitosan in aqueous solutions has been used in impregnation studies. To evaluate the retention of chitosan after an impregnation process and to evaluate the fixation of chitosan in wood a method for determination of chitosan in wood and water samples has been developed based on acidic hydrolysis of chitosan to glucosamine followed by online derivatization by o-phthalaldehyde, chromatographic separation and fluorescent detection. For wood samples the method was linear up to 45mgg−1 chitosan in wood and had a recovery of 86%. The yield of chitosan in water was 87% at 1%(w/v) concentration.

Abstract

The uptake of chitosan based impregnation solutions were tested on Scots pine (Pinus sylvestris L), Beech (Fagus sylvatica L.), Downy birch (Betula pubescens Ehrh.) and Norway spruce (Picea abies L. Karst.) in longitudinal, radial and tangential directions separately. The four chitosans tested had a fraction of acetylated residues (FA) of 0.198 and average molecular weights ranging from 18 to 129kDalton. The kinetic viscosity of the 2.4% (weight/volume) solutions at pH 5.0 was in the range of 2.95 to 28.8mm2s-1. The general trend showed that there was an increase in uptake of chitosan based impregnation solutions with decreasing viscosity, and the chitosan solution with the lowest viscosity had almost comparable uptake with water for Pine and Beech in the longitudinal direction. In general, the lower the ability for uptake of impregnation solution, the more the viscosity influences the uptake.

Abstract

Forest ecosystems provide many deliverables or benefits to society. The most obvious one is wood for the forest industry. Other benefits include berries, hunting, and recreation. More recently recognised benefits are environmental services such as carbon sequestration, water protection and biodiversity, which are without an immediate market value.On the other hand, there are pressures (e.g. climate change, air pollution, exploitation, and costs) on the ecosystem that may hamper the wood production or other benefits......