Publications
NIBIOs employees contribute to several hundred scientific articles and research reports every year. You can browse or search in our collection which contains references and links to these publications as well as other research and dissemination activities. The collection is continously updated with new and historical material.
2010
Forfattere
Andreas TreuSammendrag
Wood modification with furfuryl alcohol is an extensively investigated process and already produced commercially. Furfurylated wood is in the focus of a European project on its use for the production of high performance windows. Different wood species were treated with furfuryl alcohol and tested on water uptake, dimensional changes, leaching in water, resistance to fungal degradation, and ecotoxicity. The results show a reduced water uptake and a reduced swelling of the furfurylated wood samples. A high resistance against fungal attack of the treated wood samples can be shown. A low amount of furfuryl alcohol was leached out and the water samples of two different leaching tests showed in general low toxicity. Southern yellow pine showed good results in all of the tests and has potential for the production of window frames according to the tests performed.
Forfattere
Andreas TreuSammendrag
Furfurylation of wood samples can lead to different outcome (different chemistry) and product properties depending on parameters such as pH-value, catalyst, amount of water, time and temperature. Changes in the furfurylation process can even lead to a deterioration of product performance, such as lower durability in comparison to other furfurylated products. How is it possible to detect these changes in chemistry of a furfurylated wood product? To answer this question confocal laser scanning microscopy was used. The expectation was to detect different emissions of the auto fluorescent furfuryl alcohol if differences in chemistry exist. Additionally to the differences in emitted wavelength, the area in the wood structure of different emissions was under investigation. It was the aim to detect whether different product performance of a furfurylated product or different furfurylation processes could be related to changes in chemistry and this was expected to be visualized by CLSM.
Sammendrag
The furfurylation process is an extensively investigated wood modification process. Furfuryl alcohol molecules penetrate into the wood cell wall and polymerize in situ. This results in a permanent swelling of the wood cell walls. It is unclear whether or not chemical bonds exist between the furfuryl alcohol polymer and the wood. In the present study, five different wood species were used, both hardwoods and softwoods. They were treated with three different furfurylation procedures and leached according to three different leaching methods. The present study shows that, in general, the leachates from furfurylated wood have low toxicity. It also shows that the choice of leaching method is decisive for the outcome of the toxicity results. Earlier studies have shown that leachates from wood treated with furfuryl alcohol prepolymers have higher toxicity to Vibrio fischeri than leachates from wood treated with furfuryl alcohol monomers. This is probably attributable to differences in leaching of chemical compounds. The present study shows that this difference in the toxicity most likely cannot be attributed to maleic acid, furan, furfural, furfuryl alcohol, or 2-furoic acid. However, the difference might be caused by the two substances 5-hydroxymethylfurfural and 2,5-furandimethanol. The present study found no difference in the amount of leached furfuryl alcohol between leachates from furfurylated softwood and furfurylated hardwood species. Earlier studies have indicated differences in grafting of furfuryl alcohol to lignin. However, nothing was found in the present study that could support this. The leachates of furfurylated wood still need to be investigated further to identify the chemical differences between wood furfurylated with furfuryl alcohol monomers and furfuryl alcohol prepolymers.
Sammendrag
Measurements of heat production rate have been made on wood samples with the brown rot fungus Postia placenta at different moisture contents. The results clearly indicate that the heat production rate (a measure of respiration rate and activity) is moisture dependent. When the moisture content is decreased, less heat is produced, and when the moisture content is increased, more heat is produced. Isothermal calorimetry seems to be a measurement technique well suited to the study of rot fungal activity as a function of temperature and moisture content.
Sammendrag
One of the main challenges for new wood protection systems is to predict in a fast and accurate way service life in use class 3 (above ground) and use class 4 (in soil or fresh water contact). New environmentally benign wood protection systems are expected to have different modes of action against wood deteriorating fungi compared to the traditional preservatives, change in water sorption being one of them. Therefore it is of importance to evaluate new treated wood products in a broad range of exposure situations, also exploring the variation within use class 3 and 4. Due to the restrictions in the use of chromium containing wood preservatives, a range of studies have been published the last decade evaluating the performance of new products after laboratory or field test exposure. However, there is still a lack of studies comparing the same material in different field exposure situations. This study evaluates the efficacy of 13 novel wood protecting systems in three different above ground tests (horizontal double layer, block test and mini stakes) and two different in-ground tests (EN 252 and mini stakes). Scots pine (Pinus sylvestris L.) sapwood from the same wood source was used for all treatments. For each wood protecting system the wood specimens for all five tests were treated together in the same batch. The results after five years of field exposure are presented. In the three above ground tests no or only initial signs of decay were detected after five years (not reaching a mean rating of 1). The decay rate in soil contact was faster than above ground, but after five years only untreated wood (controls) failed in both tests. No significant difference in performance was found between the two tests in soil contact. The use of median decay rate values gave an earlier indication of performance than the use of mean decay rate values.
Sammendrag
Modified wood can provide protection against a range of wood deteriorating organisms. But we still lack information about why the modified wood is protected from microbial attack. Several hypotheses have been put forward for the mode of action against wood decaying fungi, including inhibition of action of specific enzymes, but they still need further testing. In this study gene expression of the brown rot fungus Postia placenta FPRL 280 has been monitored after 2, 4 and 8 weeks of colonization in furfurylated Scots pine (Pinus sylvestris L.) and in untreated control samples. Preliminary results are given. The main finding was that genes related to oxidative metabolic activity generally was higher in furfurylated wood compared to untreated Scots pine. Carbohydrate metabolism related expression varied. For one endo-glucanase and two β-glucosidases the expression was lower in furfurylated wood compared to untreated control, while for one glucoamylase and one glucan 1,3b glucosidase the expression was higher in furfurylated wood. The four cytochrome P450 tested, involved in breakdown of toxic compounds, gave inconsistent results between furfurylated and untreated control samples. Phenylalanine ammonia lyase and cytosolic oxaloacetase gave higher expression in control than in furfurylated samples.
Sammendrag
Scots pine (Pinus sylvestris) sapwood is per definition (EN-350-2) easy to treat. Combination with its good availability on the European markets, it is a construction and building material in demand. However, partially large differences in penetration are reported from industry and research. To keep a reliable product quality, impregnation processes aligned to the material most difficult to treat. Hence, it is crucial to know about the factors inhibiting the fluid flow into the material. Scots pine samples from a wide geographic distribution, 25 different sites in 6 different countries, have been collected and impregnated with an aqueous monomer furfuryl alcohol solution. From each of the respective sites logs of 1.3 meter in length were collected from nine trees belonging to three different breast height diameter classes. Three trees from each dominance class were chosen randomly. The log was drawn from the felled stem in a height of 1.2 meters with exact marked north/south exposition. Sapwood slabs orientated in the heaven directions, underwent a drying procedure at 40°C for 48 h and small clear samples of 20 x 20 x 50 mm were prepared. A large variation of the ratio of filling was found for the material tested. Diameter as well as sample origin seem to influence the materials permeability.
Sammendrag
Development in surface mould growth on painted/unpainted wooden claddings and acting climatic factors were investigated over a period of 3 years. Eight wood substrates, including modified, preservative-treated and untreated wood, were tested in combination with three types of paint: (1) water-borne alkyd modified acrylic paint without fungicide; (2) solvent-borne alkyd paint without fungicide; and (3) ICP (internal comparison product). One set of samples was exposed unpainted. The samples were tested according to a modified version of EN 927-3. A logistic regression model was fitted to the data. The degree of mould growth varied with exposure time, coating typology, wood substrate, temperature and relative humidity. Exposure time and coating typology contributed most to the model. After 3 years of outdoor exposure unpainted panels and panels coated with solvent-borne paint without fungicide had more mould growth than panels coated with ICP and water-borne paint without fungicide. Unpainted oil/copper–organic preservative-treated claddings had higher resistance to mould growth than other unpainted wood substrates. Coated untreated pine and coated acetylated pine were more susceptible to mould growth than other coated wooden substrates.
Sammendrag
Microbial disfigurement of coated wooden surfaces is considered a major maintenance concern and will shorten the aesthetic service life of wooden facades. The effect of the physical surface structure of a paint film when applied on wood may have an impact on the susceptibility to mould growth. Six model paints were formulated to give the following physical surface structures: glossy, matt, soft, hard, hydrophobic, and a film with air inclusion. The model paints and a standard paint, with and without fungicide, were applied on panels of Norway spruce (Picea abies L Karst.) and exposed outdoors for nearly three years according to a modified version of EN 927-3. A logistic regression model was fit to the data, and the degree of mould growth varied with exposure time and type of paint. Hard model paint was significantly more susceptible than the other model paints and had a performance close to the standard paint without fungicide. Soft model paint provided the best performance, with the least mould growth. Temperature, relative humidity, and precipitation did not significantly contribute to the model. (C) 2010 Elsevier Ltd. All rights reserved.
Forfattere
Per Otto Flæte Gry Alfredsen Kristian Bysheim Øyvind Eriksen Anders Qvale Nyrud Birger VenneslandSammendrag
Roundwood timber is raw material for numerous products. Wood based products are generally recognised as favourable regarding energy consumption and greenhouse gas (GHG) emissions. Several studies have shown that the net CO2 emissions can be reduced by using biofuels harvested from forests to substitute fossil fuels, and by using wood for building materials. Energy use and GHG emissions associated with producing roundwood can be influenced by a broad range of factors, such as silvicultural practice, topography, applied technology, forestland ownership, industrial structure, etc. This emphasizes the importance of using representative data for energy use and GHG emissions when calculating environmental impacts. The aim of this study was to investigate the embodied energy and life cycle GHG emissions of industrial softwood sawlogs in Norway, covering the production chain from tree seed to log yard. Analyses were based on activity data for the Norwegian forest sector for the year 2007. The results showed that the embodied energy and GHG emissions were low compared with the energy and CO2-equivalents stored in the roundwood (about 2%). The findings from this study can be used to inform future decisions on processes in forestry that should be focused on when planning actions to reduce energy consumption and GHG emissions. Additionally, as roundwood timber is raw material for numerous products the results can be useful when preparing documentation of environmental impacts, such as environmental product declarations, which are increasingly demanded by the market.